Iranian Journal of Geophysics

Iranian Journal of Geophysics

Geoelectric investigation and physicochemical analysis of parts of Niger Delta, Nigeria, for groundwater quality assessment

Document Type : Research Article

Authors
1 Ph.D., Department of Physics, Edwin Clark University, Kiagbodo, Delta State, Nigeria
2 Ph.D. Student, Department of Physics, University of Port Harcourt, Port Harcourt, Rivers State, Nigeria
3 Professor, Department of Physics, University of Port Harcourt, Port Harcourt, Rivers State, Nigeria
Abstract
Geoelectrical methods integrated with physicochemical analyses of borehole samples were employed to determine groundwater contamination levels in the area. Vertical electrical sounding (VES) and 2D resistivity techniques were conducted along the area's four transverses. The field data were processed using the RES2DINV and IPI2WIN software. Groundwater samples were collected from three boreholes in the area and one borehole outside the mechanic village area as a control. The results of the VES indicated that at depths beyond 18 m, resistivity greater than 200 Ωm suggested that fresh gasoline oil spills increased the electrical resistivity of the groundwater. Additionally, at depths beyond 2 m, with a resistivity range of less than 85 Ωm, biodegraded hydrocarbon spills in the auto mechanic village were evident, making the groundwater less electrically resistive. The 2D resistivity results showed two types of anomalies: high and low resistivity zones. The high resistivity zones indicate uncontaminated areas, while the low resistivity zones indicate contaminated areas. The physicochemical analyses and heavy metal groundwater samples revealed that gasoline oil infiltrated the subsoil down to the water table as a free-phase hydrocarbon. The depths of the water table and aquifer extended beyond 10 and 36 m, exhibiting high resistivity ranges greater than 287.7 and 548.6 Ωm, respectively. In conclusion, the gasoline oil spills saturate the unsaturated zone and subsequently leach into the groundwater aquifer at depths beyond 18 m, showing a high resistivity range greater than 350 Ωm.
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Adelekan B. A. and Abegunde K.D. 2011. Heavy metals contamination of soil and groundwater at automobile mechanic village in Ibadan, Nigeria. International Journal of the physical sciences, 6(5), 1045 – 1058. 
Adewoyin, O.A., Hassan. A., Aladesida, A. 2013. The impacts of auto mechanic workshops on soil and groundwater in Ibadan metropolis. Africa Journal of Environmental Science and Technology, 7(9), 891 – 898. 
Anomohanran, O. 2013. Geophysical investigation of groundwater potential in Ukelegbe, Nigeria. Journal of Applied Sciences. 13(1), 119-125. DOI: 10.3923/jas.2013.119.125.
Anomohanran, O. 2014. Determination of the Protective Capacity of the Aquitard Stratum in Some Coastline Towns of Delta State, Nigeria. Nigerian Journal of Basic and Applied Science. 22(1&2): 11-17. DOI: http://dx.doi.org/10.4314/njbas.v22i1.3.
Arubela, J. and Ajayi, A. 2012. Heavy metal pollution status of soil in some locations at Ado Ekiti, South Western Nigeria. Int J Agri Sci 2(3):256–264.
Chilton, J. 2019. Groundwater; in water quality assessments, in: D. Chapman (Ed.), A Guide to the Use of Biota, Sediments, and Water in Environmental Monitoring - Second Edition, UNESCO/WHO/UNEP, 1996 https://www.who.int/iris/bitstream/10665/41850/1/0419216006 _ eng.pdf Accessed 26th Au- gust 2019
Darma, A., Ibrahim, S., Sani, A., Zandi, P., and Yang, J. 2022. Appraisal of lead (Pb) contamination and potential exposure risk associated with agricultural soils and some cultivated plants in gold mines. Environ Syst Res 11:14. https://doi.org/ 10.1186/s40068-022-00259-3.
Doust, H, and Omatsola, E. 1990. Niger Delta. In: Edwards, J.D. and Santogrossi P.A. (eds), Divergent/Passive Margin Basins, American Association of Petroleum Geologists Memors, U.S.A. 48, 201-238.
Ebong D E., Anthony E. A., Chimezie N. E. and Job G. U. 2017. Groundwater quality assessment using geoelectrical and geochemical approach; case study of Abi area, southeastern Nigeria. Applied water science, 7(5), 2463 – 2478.
Ekeleme, A.C., Ibearugbulem, O.H., Ugwuegbulam, J.C. 2015. Groundwater quality in parts of Owerri Imo State in South-Eastern Nigeria, Inter. J. Civil Eng. Const. Chem. Predict. Estate Manag. 3 (1), 62–72.
Etu-Efeotor, J.O. 1981. Preliminary hydro-geochemical investigation of subsurface water in parts of the Niger Delta.  Journal of Mining and Geosc. Soc. 108 – 110.
Fatoke, O.A. 2010. Sequence stratigraphy of the Pliocene strata and shelf margin deltas of the eastern Niger Delta, Nigeria. Ph.D. dissertation (Unpubl), University of Houston, Texas.
Ibrahim, D., Abdullahii, S. U., Adamu, I. U., Dazi, L. L., Salihu, A. I., and Simon, I. A. 2019.
             Heavy metal contamination of soil and ground water at automobile mechanic workshops in Borno 
             State, Nigeria. Nigerian Research Journal of Chemical Sciences, 7, 197 –
              213.
Ipeaiyeda, A.R. and Dawodu, M. 2008. Heavy metals contamination of topsoil and dispersion in them vicinities of reclaimed auto-repair workshops in Iwo, Nigeria. Bull Chem Soc. Ethiopia;22(3):339-348.
Iwegbue C.M. 2007. Metal fractionation in soil profiles at automobile mechanic waste dumps around Port Harcourt. Waste Manag Res, 25(6):585-593.
Kidman, R.L. and Boehlecke, R. 2011. Evaluating Petroleum Hydrocarbon-contaminated Soil. WM 2011 Conference, February 27–March 3, 2011, Phoenix, AZ.
Longe, E.O. and Balogun, M.R. 2010. Groundwater Quality Assessment near a Manucipal Landfill, Lagos, Nigeria . Research Journal of Applied Science, Engineering and Technology,2, 39-44.
Michele, L.W., Ronald, R.C., and Michael, E.B. 1999. The Niger Delta petroleum system: Niger Delta Province, Nigeria, Cameroon and Equatorial Guinea Africa, USGS open files report, 118.
Muze, N.E., Opara, A.I., Ibe, F.C. and Njoku, O.C. 2020. Assessment of the geo-environmental effects of activities of auto-mechanic workships at Alaoji Aba and Elekahia Port Harcourt, Niger Delta, Nigeria. Environmental Analysis Health and Toxicology. 35(2):1-12
Nebo C.U., Udom G.J. and Ehirim C.N. 2018. Contaminant impact assessment of automobile mechanic workshop on soil and groundwater resource in Port Harcourt, Nigeria. IJSIT, 7(3), 451 – 463. 
NSDQW 2007. Nigerian Standard for Drinking Water Quality, Nigerian Industrial Standard NIS 554 Standard Organization of Nigeria, Lagos.
Nuhu, G.O. 2009. Geology and mineral resources of Nigeria. Springer Dordretch, NewYork, 112.
Nwachukwu, S. O. 1972. The Tectonic Evolution of the Southern Portion of the Benue Trough, Nigeria: Geol. Mag. 109, 411 - 419.
Nwankwo, C.N., Emujakorue G.O. 2012. Geophysical Methods of Investigating Groundwater and Subsoil Contamination, Case Study: Ahoada, South-South Nigeria. American Journal of Environmental Engineering, 2(3), 49-53.
Okiongbo, K.S. and Ogobiri, G. 2011. Geoelectric Investigation of Groundwater Resources in Parts of Bayelsa State, Nigeria. Research Journal of Environmental and Earth Sciences. 3(6): 620-624.
Okon P., Udeme P., Udeme I., and Itoro S. 2019. Geophysical Investigation of Groundwater Potential in Akwa Ibom State Polytechnic Geophysical Investigation of Groundwater Potential in Akwa Ibom State Polytechnic Campus, Ikot Osurua Akwa Ibom State, South-South Nigeria Using Electrical Resistivity Method. International Journal of Environmental Studies and Safety Research, 4(2), 60-68.
Ololade I.A. 2014. An assessment of heavy-metal contamination in soils within auto-mechanic workshops using enrichment and contamination factors with geoaccumulation indexes. J Environ Protection 2014; 5:970-982.
Oloruntoba, E.O., Ogunbunmi, T.O. 2020. Impact of informal auto-mobile mechanic workshops activities on ground water quality in Ibadan, Nigeria. J Water Resour Prot 12:590–606
Olugboji, O.A., and Ogunwole, O.A. 2008. Use of spent engine oil. AU JT; 12(1): 67-71.
Onu, N.N., Opara, A. I., and Ehirim, C.N. 2012. Delineation of Active Fractures in a Gully Erosion Area Using Geophysical Methods: Case study of the Okigwe – Umuahia Erosion Belt, Southeastern Nigeria. Inter. J. Sci. Tech., 2(4): 168 – 177.
Oseji J.O., Atakpo E.A, Okolie E.O. 2005. Geoelectric investigation of the aquifer characteristics and groundwater potential in Kwale, Delta state, Nigeria. J. Appl. Sci. Environ. Mgt., 9 (1) 157 – 160.
Petters, S.W., and Ekweozor, C. M. 1982. Petroleum geology of Benue Trough and southeastern Chad Basin, Nigeria: Am. Assoc. Petrol. Geol. Bull., 66(1), 1141 –1149.
Reijers, T.J. 1996. Stratigraphy and sedimentation of Niger Delta, Geologos 17(3), 136-158.
Simpson, A. 1955. The Nigerian Coal field: The Geology of parts of Onitsha, Owerri, and Benue Provinces: Geological Survey of Nigeria Bulletin 24, 85-92.
Therese, N., Edet, A.E., and Ekwere, S.J. 2007. Concentrations of heavy metals and hydrocarbons in groundwater near petrol stations and mechanic workshops in Calabar metropolis, southeastern Nigeria. Environmental Geosciences. 14(1). 15 – 29.
Tuttle, M., Charpentier, R., and Brownfield, M. 2015. The Niger Delta Petroleum system: Niger Delta, Province, Nigeria, Cameroon, and Equatorial Guinea Africa, United State Geological Survey (USGS), 22.
Uguru, H., Akpokodje, O.I., Rokayya, S., Amani, H.A., Almasoudi, A. and Almasoudi, A.G. 2022a. Comprehensive assessment of the effect of various anthropogenic activities on the groundwater quality. Science of Advanced Materials. 4:462–474.
Vwioko, D.E., Anoliefo, G.O. and Fashemi, S.D. 2006. Metals concentration in plant tissues of Ricinus communis L. (Castor Oil) grown in soil contaminated with spent lubricating oil. J Appl Sci Environ Manag., 10(3): 127-134.
Wang J., Jia C.R., Wong, C.K., Wong, P.K. 2000. Characterization of polycyclic aromatic hydrocarbon created in lubricating oils. Water Air Soil Pollut; 120(3-4):381-396.
Weber, K.J. and Daukoro, E. 1975. Petroleum Geology of the Niger Delta. Tokyo 9th World Petroleum Congress Proceedings, 2: 209-211.
WHO, 2004. Guidelines for Drinking Water Quality 1(3) WHO Geneva.

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